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6
UNITEX nr. 1 - 2014
(grant No. IWT 095024) and LEDcure (grant No. IWT
120626).
Contact information:
Frederik Goethals, Centexbel Gent, e-mail: frg@
centexbel.be
a
Centexbel, Technologiepark 7, 9052 Zwijnaarde,
Belgium
b
STFI, Annaberger-Strasse 240, D-09125 Chemnitz,
Germany
c
TNO, Schoemakerstraat 97, P0 6024, 2600JA Delft,
The Netherlands
References
1) http://www.fusionuv.com/uvlearningcenter.aspx?id=206
2) Brinker, C. J. & Scherer, G. W. (1990). Sol-gel science. San Diego: Academic
Press, INC.
Application of microcapsules into textiles, the
new trend for added value performance
Devan Chemicals nv - Isabel Cardoso & Raquel Vieira
Performance textiles are a new paradigm for the textile
industry and represent one of the fastest growing
sectors of the industry. Market growth is being fuelled
by the emergence of new bres, new fabrics and
innovative process technologies. The market is also
being boosted by changes in consumer lifestyles;
people are living longer and spending more time on
leisure activities. Microencapsulation technology opens
up new marketing opportunities for textiles and home
furnishings.
The move by the more developed countries into textiles
with new properties and added value has encouraged
the industry to use microencapsulation processes as a
means of imparting nishes and properties on textiles
which were not possible or cost-effective using other
technology.
But while customers are always looking for something
different, retailers will need to be enlightened on the
technical benets of these treatments and show how
the premium-priced end products can be marketed
effectively.
The microencapsulation technology
The new patented technology of Devan’s group
consists on the application of active microcapsules with
functional reactive groups on the shell surface, which
can react within the chemical groups of the bres, and
be applied by any conventional textile nishing process
such as padding, exhaustion or spraying. The chemical
bond of the microcapsules with the bres confers a
very high resistance to washing during the life time of
the article.
The major application is the microencapsulation of
active cores as fragrances, skin-care components,
insect repellents and phase change material (PCM).
1. Phase Change Materials microcapsules
Devan’s THERMIC™ technology is based on the
microencapsulation of PCMs (phase change materials).
These materials, as their name indicates, possesses
the ability to change their physical state (phase) from
“solid to liquid” and from “liquid to solid”, within a
certain temperature range, in response to ambient
temperature oscillations. These materials absorb heat
when the temperature goes up, storing this energy
temporarily, and release the energy as heat when the
temperature cools down.
Fig. 1: the THERMIC™ technology is based on the microencapsulation of PCMs
(phase change materials)
They can be seen as a “thermal battery”, analogous
to electric batteries which are charged, then store
and release that energy on demand. In the case of
THERMIC™, the thermal batteries charge when thermal
energy is available (e.g. through body heat) and release
this thermal energy when the temperature (e.g. the
external temperature) drops below a certain point.
PCM’s have to be contained within a closed environment
(microcapsule) as when they change phase, they pass
from solid to the liquid state. If the PCM were not
encapsulated the liquid PCM would ow away.
Depending upon the application of these materials, the
nature of the capsule may change. If the application
has to maintain the physical characteristics of the
substrate, as in the case of textiles, the container has
to be very small. For this reason, microcapsules are
mostly used for textile applications. As microcapsules
are so small, a thousand times smaller than an average
human hair, they can be applied to textile substrates.
The challenge of applying PCMs on textiles is to apply
as many microcapsules per square meter as possible,
without changing the other properties of the fabric
(hand, breathability, tear strength,…).
By using the Devan´s group reactive technology
system, the disadvantages that are caused by the use
of binders, will be avoided and the textile will maintain
its properties. Also, the chemical bond of the reactive
microcapsules with the bres will enable washing
during the life time of the article. Wash fastness tests
were done up to 50 washes (40º C) with an average
loss of microcapsules of approximately 10-20%.
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